Standard Jet DBnb` Ugr@?~1y0̝cßFNo7]М("`T{6߱w`C;34y[!|*|~f_Љ$g'DeFx -bT4.0 GcOOOOOOO< (   x e Q > +   z g T @-}iVC/ lXE2¨¨¨• p%= h;=h: =h: +k5d+k5dBf0Sn;$eRFC]GWlq2)d;au@^` pފΚy Y Q+Wm=p +k5d+k5dBf0Sn;$eRFC]GWlq2)d;au@^` pފΚy Y Q+Wm=p +h: +k}dxGBfYtˮdRFC]GWlq2G&c 7р%[QjE^` pފΚy Y Q+Wm=p +i: h: k}dxGBfYtˮdRFC]GWlq2G&c 7р%[QjE^` pފΚy Y Q+Wm=p i: h: k}dxGBfYtˮdRFC]GWlq2G&c 7р%[QjE^` pފΚy Y Q+Wm=p i: h: k}dxGBfYtˮdRFC]GWlq2G&c 7р%[QjE^` pފΚy Y Q+Wm=p i: h: k}dxGBfYtˮdRFC]GWlq2G&c 7р%[QjE^` pފΚy Y Q+Wm=p i: h: k}dxGBfYtˮdRFC]GWlq2G&c 7р%[QjE^` pފΚy Y Q+Wm=p i: h: k}dxGBfYtˮdRFC]GWlq2G&c 7р%[QjE^` pފΚy Y Q+Wm=p i:  h:  k}dxGBfYtˮdRFC]GWlq2G&c 7р%[QjE^` pފΚy Y Q+Wm=p  i:  h:  k}dxGBfYtˮdRFC]GWlq2G&c 7р%[QjE^` pފΚy Y Q+Wm=p  i: h: k}dxGBfYtˮdRFC]GWlq2G&c 7р%[QjE^` pފΚy Y Q+Wm=p i: h: k}dxGBfYtˮdRFC]GWlq2G&c 7р%[QjE^` pފΚy Y Q+Wm=p i: <h: <k}dxGBfYtˮdRFC]GWlq2G&c 7р%[QjE^` pފΚy Y Q+Wm=p <i: ;h: ;k}dxGBfYtˮdRFC]GWlq2G&c 7р%[QjE^` pފΚy Y Q+Wm=p ;i: :h: :k}dxGBfYtˮdRFC]GWlq2G&c 7р%[QjE^` pފΚy Y Q+Wm=p :i: h: k}dxGBfYtˮdRFC]GWlq2G&c 7р%[QjE^` pފΚy Y Q+Wm=p i: h: k}dxGBfYtˮdRFC]GWlq2G&c 7р%[QjE^` pފΚy Y Q+Wm=p i: h: k}dxGBfYtˮdRFC]GWlq2G&c 7р%[QjE^` pފΚy Y Q+Wm=p i: h: k}dxGBfYtˮdRFC]GWlq2G&c 7р%[QjE^` pފΚy Y Q+Wm=p i: h: k}dxGBfYtˮdRFC]GWlq2G&c 7р%[QjE^` pފΚy Y Q+Wm=p i: h: Tk}dxGBfYtˮdRFC]GWlq  Y_S __ Y   Y Y  Y Y  Y  DY  Y   Y  Y  Y a Y d Y 2Y  Y   Y  jY ConnectDatabaseDateCreateDateUpdate FlagsForeignNameIdLvLvExtraLvModule LvPropName OwnerParentIdRmtInfoLongRmtInfoShortTypeniYYIdParentIdName        heat exhaustion, such as the lack of sweating, the color of the skin (red), and the rise in body temperature. Heat stroke is a medical emergency that requires immediate medical attention.ArialmC`<a bX i kt9_2d378"`a.bXcd eLabel74Required Action ArialGrp1` PageHeader`[Event Procedure]Detail m`tbcSectionSectionmbckColData5SiteDetailPicklist.ColData5m5`<bck ColData1a!SiteDetailPickListChoice.ColData1Grp1m5`bck ColData2a!SiteDetailPickListChoice.ColData2Grp1m5`\ bck ColData3a!SiteDetailPickListChoice.ColData3Grp1m5`bck ColData4a!SiteDetailPickListChoice.ColData4Grp1mbckColData3SiteDetailPicklist.ColData3mbckColData2SiteDetailPicklist.ColData2mbckColData1SiteDetailPicklist.ColData1mbck ColData4SiteDetailPicklist.ColData4mbck ColData6SiteDetailPicklist.ColData6mbck ColData7SiteDetailPicklist.ColData7m5`bXck ColData5a!SiteDetailPickListChoice.ColData5Grp1` PageFooter` ReportFooterͬ'؉oCu3ReportHeaderdLab1dLab2dLabel57dLabel30mt9_3dLabel60dLabel61dLabel58m t9_2d Label74 PageHeader Detailm SectionmColData5mColData1amColData2amColData3AmColData4amColData3mColData2mColData1mColData4mColData6mColData7mColData5aPageFooterReportFooterSite NameSiteDetailPicklist.ColData1SiteDetailPicklist.ColData2SiteDetailPicklist.ColData3 SiteDetailPicklist.ColData5!SiteDetailPickListChoice.ColData1"SiteDetailPickListChoice.ColData2#SiteDetailPickListChoice.ColData3$SiteDetailPickListChoice.ColData4%SiteDetailPicklist.ColData4&SiteDetailPickListChoice.ColData50:<=Babc e gOhi<jQ'k:|@SELECT SiteDetailPicklist.[Site Name], SiteDetailPicklist.Section, SiteDetailPicklist.ColData1, SiteDetailPicklist.ColData2, Blob MHPropDatapHTypeInfoqH688‚8OYS^Y Y Y  Y 2ACMFInheritableObjectIdSID  AtYObjectIdy`2Aw?N 7D`:ŻJ&)0grkfl a3b3{mY9U4,RaDKXK|+=k~ğsʑv|G&6ӽވ{ [6Z6KocJ3RʥE)`ZC(HLSL94"}{s.CP.\>M `^|:[?N!xx&LN TM[V2׏Ο4mh B#HeN?՘ ӥ6{h6{[D"_{SEI⾽JAV-oDZ@4|e* &yH4P nwLP<hZ]I)POG KƌHM^ip%<| `}qcƁ$מz휙\Ėk,T0ddf) WEb2`Q]^" tc0BP]7E)+ $1dj&Xd0DKW""<8>T[8qiΒFJWz:]vJMpM^O-1&vܴrtr}4/026OU^~>צ[E%z+;~zu+{]˳|(>?@ABCDEFGHIJKLMNOPQRSTUVWXYZ[\]^_`abcdefghijklmnopqrstuvwxyz{|}~      !"#$%&'()*+,-./0123456789:;<>=?@ABCDEFGHIJKLMNOPQRS T U V W XYZ[\]^_`abcdefghij k!l"m#n$o%p&q'r(s)t*u+v,w-x.y/z0{1|2}3~456789:;<=>?@ABCDEFGHIJKLMNOPQRSTUVWXYZ[\]^_`abcdefghijklmnopqrstuvwxyz{|}~                                  ! 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" # $ % & ' ( ) * + , - . / 0 1 2 3 4 5 6 7 8 9 : ; < = > ? @ A B C D E | | | |  | |  | | | |! |" |#Y @ @ @ @ @ @ @ @ @ @ @ @ @ ; G; G; G; G; G; G; G; G; G ; G ; G ; G ;  G ;  G;  G;  G;  G; G; G; G; G; G; G; G; G; G; G; G; G; G; G; G ; G!; G"; G#; G$; G< G%< G'< G(< G)< G*< G+< G,< G-< G.< G/<  G0<  G1<  G2<  G3<  G4< G5< G6< G7< G8< G9< G:< G;< G<< G=< G>< J< J< J< J< J< J< J< J<  J<! J <" J <# J <$ J <% J <& J<' J<( J<) J<* J<+ J<, J<- J<. J</ J< J< G&= J= J= J= J= J= J= J = J!= J"= J#= J$= J%=  J&=  J'=  J(=  J)=  J*= J+= JTypeInfoPropData58 ``t Procedure]^ @&select * from SiteDetailPickListChoice[Event Procedure]HaspAriald2eAriale2f2g12347hghAriali1ghj1ghk1l234:m4Cn2Arialo2AArialp5r34zij MS Sans Serif{5Arial` FormHeader`;Detailo5]bc<dedf,l "";"";"10";"200"ColData1ColData1 Table/Query5select PickList from Picklist where [Section]="16_2"; MS Sans Serifm7`bi kRecNoRecNom7`| bi kColData2ColData2m7`Xbi k ChoiceRecNo ChoiceRecNom7`<bdc,k ColData1aColData1m7` a<b i kColData3ColData3` FormFooterͬs7S+4nFJX4GFormHeaderDetailoColData1mRecNomColData2mChoiceRecNomColData1amColData3FormFooter ColData4 ColData5 2n @@+ 6D6F:BLBS@LB>JOJL8S86F>68SBHF6OF<6SOL8O@<>:S>>O@F:SSM:O>>O8OLL>M+ +;K[ t+ DJDS8OD:OQDL>8BQL@LFDDO>Q6DQ:F>DBQJBOFHOB>OM@>8BSB+ +;K[ t+ L8BQMD::MLLM>OO6JO@QH:OO6SSSJQSF+ +;K[ t+ M688L8FMM68HLOLOBBOQML8S::>B+ +;K[ t`6                         ! m % & ' ( ) * + , - . / 0 1 2 3 4 5 6 7 8 9 : ; < = > @ A B E F G H I J K L M N O P Q R S T U V W X Y Z [ \ ] ^ _ ` a b d e f g h i j k o p q r s t u v w x y z { | } ~  ishing and maintaining site security during non-working hours ?Arialm457UC`LaXb,k tmpSectionm7U`aXb,ckchkfrmh1U`aXbnc2iUpdDataUpdData(ڭ ڭз ڭ pڠ 03 з 03 333 333 0   H Save Datah1U`<ab c,ibtnCloseDone[Event Procedure]d5U`<a<b !cd Label31}What is the name or job title of the person responsible for establishing and maintaining site security during working hours ?Ariald5]`,abc,d Label32SAutomatically filled based on information provided earlier. Edit name if necessary.Arialm7W`(aXb c,i AutoFill10Len(IIf(IsNull([AutoFill1]),"",[AutoFill1]))<2560The length of this field is 255 characters only.m7]C`(ab c,i k AutoFill20Len(IIf(IsNull([AutoFill2]),"",[AutoFill2]))<2560The length of this field is 255 characters only.d5W`,abc,d Label35SAutomatically filled based on information provided earlier. Edit name if necessary.Arialp3U`<ab(#c dsub1Form.Chap3Sub2a[Site Name];Section[Site];[tmpSection1]Grp1_2p3U`<adb(#c dSub2Form.Chap3Sub2a[Site Name];Section[Site];[tmpSection2]Grp1_2m457UC`DaXb,kSitem457UC`aXb,k tmpSection1m457UC`PaXb,k tmpSection2ͬH1+&J{Zt|Detaild Label1mtmpSectionmchkfrmh UpdDatah btnClosed Label31d Label32mAutoFill1m AutoFill2d Label35p sub1p sub2m SitemtmpSection1mtmpSection2St  kYmQOQmJY^ tkYmQOQmJY^fYM\^Ykm tkYmQOQmJY^fYM\^YkmMWdYMQ tkYmQOQmJY^fYM\^YkmMWdYMQ^Ykm tkYmQOQmJY^fYM\^YkmfidM tkYmQfQikdbbQ^ tkYmQmQum t MS Sans SerifH Save Data`,Detailm7]` b ce Site Name Site Name Site_Namem7U`b cekSectionSectionm7`<a<b kColData4ColData4` FormFooterͬJrf:AlFormHeaderd Label1mtmpSectionmchkfrmh UpdDataDetailmSite_NameSite NamemSectionmColData4 FormFooter ColData1 ColData2 ColData3 ColData5ColData6ColData7ColData8ColData9ColData10RecNoͬ! p۾bA6sDetaild QuestionBlob NTypeInfo/ rPropData9 98   N') !"#$%&(79+,-./01234568KM;<=>?@ABCDEFGHIJLOU}PQRST_aWXYZ[\]^`bfcdey|hijklmnopqrstuvwxz{02=Babce g"hij)k8e@Zselect * from SiteDetailPicklist where [Site Name]=Forms![Main]![Site] and Section="6_2g"; [Event Procedure][Event Procedure][Event Procedure][Event Procedure]Ariald2hgh MS Sans Serifj1ghm45n2p5` Detaild5U`<abc,d eXQuestionOperational PhaseArialm7]`bh SectionData SectionDatah1`Tbnc2iUpdDataUpdData,(ڭ ڭз ڭ pڠ 03 з 03 333 333 0   H Save Datam7]`axb,ckchkfrmm457UC`,a<b,k tmpSectionm457UC`a<b,kSectionSectionm457C`a<b,k Site Name Site Name Site_Namen3W8`a<bdcKdj lListInOn Table/Query0;3298[Event Procedure]n03W8`abdcKdj l ListOutOn Value List0;3298[Event Procedure]h1U`abcni AddListOnAddc @ @ kYmQ tkYmQ tkYmQ tkYmQ tkYmQOQmJY^fYM\^Ykm tkYmQOQmJY^fYM\^Ykm tkYmQOQmJY^fYM\^YkmMWdYMQ t Label78jColData6d Label81kColData4idoAd Label84idoBd Label86d Label87d Label88d Label89kColData5iup1d Label92iup2d Label94iup3d Label50iup4d Label52d !Label95o"ColData7m#ColData8d $Label98o%ColData3d &Label46d 'Label100k(ColData9i)up1Ad *Label1Ai+up2Ad ,Label105i-up3Ad .Label107i/up4Ad 0Label109d 1Label110o2ColData11m3ColData12d 4Label113o5ColData10d 6Label115d 7Label116d 8Label117d 9Label127o:ColData15m;ColData16d <Label130o=ColData14d >LabelPPEd ?LabelDownh @btnHelp5d ALabel135mBChoiceRecNoiCup1Bd DLabel1BiEup2Bd FLabel2BiGup3Bd HLabel3BiIup4Bd JLabel4BeKBox147mLColData13MFormFooter02=Babce gFhiij&k q@Zselect * from SiteDetailPicklist where [Site Name]=Forms![Main]![Site] and Section="7_4f";#PPE Levels: Ensembles and Materials[Event Procedure][Event Procedure]HaspArial[Event Procedure] d2hgh MS Sans Serifi1ghjBlob [6 TypeInfo PropData108`}`}W1ghk1m45n2o2p5` FormHeader`xDetailm7U`(a<bhk SectionData SectionDatam7]`ab,ckchkfrmm457]C`ab,k tmpSectionm457]C`ab,kSectionSectionm457UC`a<b,k Site Name Site Name Site_Namem7UC`abc,i ColData1ColDs'0d _ Z g  ~K s z ' .3036;B?             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Y@)@ YA)A YB)B YC)C YD)D YE)E  YF)F dYG*G YH*H YI*I YJ*J YK*K YL*L YM*M  YN*N YO+O  YP+P dYQ,Q YR,R YS,S YT,T YU,U  YV,V (YW,W 0YX,X 8YY,Y @YZ,Z HY[,[ PY\,\ XY],] `Y^,^ hY_,_ p Y`,` dUIDCAS NumberUN Number$Main Chemical NameFormula Molecular WeightBoiling PointMelting PointVapor PressureGeneral DescProperties NFPA Fire Rating$NFPA Health Rating,NFPA Reactivity Rating0NFPA Special InstructionFirst Aid,Nonfire Spill ResponseFirefightingReactivityTLV-TWA ppmTLV-TWA mg/m3TLV-STEL ppmTLV-STEL mg/m3TLV-C ppmTLV-C mg/m3TLV NOTESPEL-TWA ppmPEL-TWA mg/m3PEL-STEL ppmPEL-STEL mg/m3PEL-C ppmPEL-C mg/m3PEL NOTESREL-TWA ppmREL-TWA mg/m3REL-STEL ppmREL-STEL mg/m3REL-C ppmREL-C mg/m3REL NOTESIDLH ppmIDLH mg/m3IDLH CA/LEL Skin DesignationOSHA SkinNIOSH SkinACGIH Skin"EPRG1/EPRG2/EPRG3CarcinogenSymptomsHealth EffectsTarget OrganSynonyms"Conversion Factor(Physical DescriptionNotes 2Flash Point(Ionization Potential(Re<"GI 7 ~  W  h t/5f!RTVhhh@@ @  @@@ @`01  @  @ @  @  HJk @@@A   @@@ P@P  @@(@ @@0D@@@@ H  "@   Ba"@@ @ܘy{Wl;U#Sok9z5MA|+2Ak9ln7uӛsǻmO\sv?xK͸`p6g㙛6ca2l6b:ڲp,?6Zf*rMGsBΠ9;1o@@@   @ @ @@ @@@@  @@@ @  @ ` "@ "@ B@@$B $@D $@@ @D@J$" $B  @  A2@@@ B @@ @ Dw"Vh ,D!ND@ -LVAL;g) z P  Z 0  \ 2 g b9)mCo4 `6 Bd:8 TLV-TWA mg/m3$87-88 TLV-STEL ppm(87-88 TLV-STEL mg/m387-88 TLV-C ppm"87-88 TLV-C mg/m387-88 TLV Notes 87-88 ACGIH Skin86 RESPIRABLE FRACTION, 15 mRESPIRABLE FRACTION, 15 mg/m3 TOTAL DUST. 50 MPPCF.RESPIRABLE FRACTION, 15 mg/m3 TOTAL DUSTRESPIRABLE FRACTION; 15 mg/m3 TOTAL DUSTRESPIRABLE FRACTION, 15 mg/m3 TOTAL DUSTRESPIRABLE FRACTION, 15 mg/m3 TOTAL DUSTRESPIRABLE FRACTION, 15 mg/m3 TOTAL DUSTMINIMIZE EXPOSURE TO NIAX(R) CATALYST ESN, COMPONENTS AND FORMULATIONS CONTAINING EITHER COMPONENTTWA = 20 mppcf OR (80 mg/m3)/(%SiO2)as BENZENE SOLUBLE FRACTION (ANTHRACENE, BaP, PHENANTHRENE, ACRIDINE, CHRYSENE, PYRENE); SEE 1910.1002 (DEFINITION)RESPIRABLE FRACTION, 15 mg/m3 TOTAL DUSTRESPIRABLE FRACTION, 15 mg/m3 TOTAL DUSTRESPIRABLE FRACTION, 15 mg/m3 TOTAL DUSTRESPIRABLE FRACTION, 15 mg/m3 TOTAL DUSTRESPIRABLE FRACTION, 15 mg/m3 TOTAL DUSTMINIMIZE EXPOSURE TO NIAX (R) CATALYST ESNRESPIRABLE FRACTION, 15 mg/m3 TOTAL DUSTRESPIRABLE FRACTION, 15 mg/m3 TOTAL DUSTRESPIRABLE FRACTION, 15 mg/m3 TOTAL DUSTPEAK = 300 ppm FOR A 5 MINUTE INTERVAL DURING ANY 2 HOURSPEAK = 50 ppm FOR A 10 MINUTE INTERVAL DURING AN 8-HOUR SHIFTRESPIRABLE FRACTION, 15 mg/m3 TOTAL DUSTas Pb (SEE 29 CFR 1910.1025) OR A CEILING OF 0.1 mg/m3 as CrO3RESPIRABLE FRACTION, 15 mg/m3 TOTAL DUSTRESPIRABLE FRACTION, 15 mg/m3 TOTAL DUSTPEAK = 100 ppm FOR A 30 MINUTE INTERVAL DURING AN 8-HOUR SHIFTSEE 29 CFR 1910.1017; 5 ppm IS THE AVERAGE CONCENTRATION THAT MUST NOT BE EXCEEDED DURING ANY PERIOD NOT EXCEED 15 MINUTESSEE 29 CFR 1910.1027, FOR OPERATIONS/SEGMENTS WHERE THE STANDARD IS STAYED/NOT IN EFFECT PEL's ARE LOCATED IN 29 CFR 1910.1000 TABLE Z-2 ( DUST: 8-HR TWA=0.2mg/m3, C=0.6mg/m3; FUME: 8-HR TWA=0.1mg/m3, C=0.3mg/m3)PEAK = 0.025 mg/m3 FOR 30 MINUTES DURING AN 8-HOUR SHIFTRESPIRABLE FRACTION, 15mg/m3 TOTAL DUSTPEAK = 300 ppm FOR A 5 MINUTE INTERVAL DURING ANY 3 HOURSSEE 29 CFR 1910.1028, FOR INDUSTRIES EXEMPT FROM THIS STANDARD THE PELs ARE LOCATED IN 29 CFR 1910.1000 TABLE Z-2 (8-HR TWA=10 ppm, C=25ppm, PEAK=50ppm FOR A 10 MINUTE INTERVAL DURING AN 8-HOUR SHIFT)RESPIRABLE FRACTION, 15 mg/m3 TOTAL DUSTRESPIRABLE FRACTION, 15 mg/m3 TOTAL DUSTPEAK = 200 ppm FOR A 5 MINUTE INTERVAL DURING ANY 4 HOURSCOAL TAR PITCH VOLATILE; SEE 29 CFR 1910.1002 (DEFINITION)RESPIRABLE FRACTION, 15 mg/m3 TOTAL DUSTTWA TOTAL DUST = (30mg/m3)/(%SiO2+2), TWA RESPIRABLE FRACTION = (10mg/m3)/(%SiO2+2)RESPIRABLE FRACTION, 15 mg/m3 TOTAL DUSTRESPIRABLE FRACTION, 15 mg/m3 TOTAL DUSTRESPIRABLE FRACTION, 15 mg/m3 TOTAL DUSTRESPIRABLE FRACTION, 15 mg/m3 TOTAL DUSTEXCEPT TELLURIUM HEXAFLUORIDE AND BISMUTH TELLURIDERESPIRABLE FRACTION, 15 mg/m3 TOTAL DUSTSTEL = 1 f/cc (30 MINUTES); SEE 29 CFR 1910.1001RESPIRABLE FRACTION, 15 mg/m3 TOTAL DUSTPEAK = 300 ppm FOR A 5 MINUTE INTERVAL DURING ANY 3 HOURSRESPIRABLE FRACTION, 15 mg/m3 TOTAL DUSTSTEL (30 MINUES) = 1 f/cc, SEE 29 CFR 1910.1001RESPIRABLE FRACTION, 15 mg/m3 TOTAL DUSTVOLUNTARY TWA = 1 f/cc, RESPIRABLE FIBERS, UNDER A VOLUNTARY HEALTH AND SAFETY PARTNERSHIP PROGRAM WITH MANUFACTURERS (NORTH AMERICAN INSULATION MANUFACTURERS ASSOCIATION)PEAK = 500 ppm FOR A 10 MINUTE INTERVAL DURING AN 8-HOUR SHIFTPEAK = 200 ppm FOR A 5 MINUTE INTERVAL DURING ANY 3 HOURSSEE 29 CFR 1910.1051; 29 CFR 1910.19 (1)PEAK = 50 ppm FOR A 5 MINUTE INTERVAL DURING AN 8-HOUR SHIFTRESPIRABLE FRACTION, 15 mg/m3 TOTAL DUSTTWA TOTAL DUST = [(30mg/m3)/(%SiO2+2)], TWA RESPIRABLE FRACTION = [(10mg/m3)/(%SiO2+2)]RESPIRABLE FRACTION, 15 mg/m3 TOTAL DUSTVOLUNTARY TWA = 1 f/cc, RESPIRABLE FIBERS, UNDER A VOLUNTARY HEALTH AND SAFETY PARTNERSHIP PROGRAM WITH MANUFACTURERS (NORTH AMERICAN INSULATION MANUFACTURERS ASSOCIATION)PEAK = 600 ppm FOR A 5 MINUTE INTERVAL DURING ANY 3 HOURS!LVAL r ) Z K d5)xKnU-88 TLV-TWA ppm&87-88 TLV-TWA mg/m3$87-88 TLV-STEL ppm(87-88 TLV-STEL mg/m387-88 TLV-C ppm"87-88 TAIR AND WATER REACTIONS: Reacts slowly with wAIR AND WATER REACTIONS: Reacts slowly with water to form phosphoric acid (REACTIVITY, 1999)STABILITY: Protect from light. Low stability.REACTIVITY: Acts as an oxidizing agent. (NTP, 1992)STABILITY: Oxidizes on exposure to air.REACTIVITY: Can react with oxidizing materials. (NTP, 1992)STABILITY: This chemical is sensitive to heat. It is also sensitive to light.REACTIVITY: This chemical is incompatible with strong oxidizers and strong alkalies. It will attack some forms of plastics, coatings and rubber. (NTP, 1992)STABILITY: Stable under normal laboratory conditions.REACTIVITY: May react with oxidizing materials. (NTP, 1992)Contact with oxidizers can cause fires and explosions.Polymerization: Will not polymerize. (USCG, 1999)Dissolves rubber and plastics. (USCG, 1999)STABILITY: This compound is stable under normal laboratory conditions. (NTP, 1992)STABILITY: This compound should be stable under normal laboratory conditions. (NTP, 1992)CHEMICAL PROFILE: Reacts violently with strong oxidants. (Handling Chemicals Safely 1980. p. 928). (REACTIVITY, 1999)STABILITY: This chemical is stable under normal laboratory conditions.REACTIVITY: This compound can react with oxidizing materials. (NTP, 1992)STABILITY: This compound oxidizes in air. It is also light sensitive especially in solution. Slow air oxidation is catalyzed by light (visibly darkens). This chemical may also be somewhat hygroscopic. It will polymerize if heated above 257 F. Solutions of this chemical in water, DMSO, 95% ethanol or acetone should be stable for 24 hours when protected from air and light.REACTIVITY: This compound is incompatible with strong oxidizing agents. It is also incompatible with acids. It will catalyze isocyanate-alcohol and epox reactions. (NTP, 1992)CHEMICAL PROFILE: Base-catalysed reactions of isocyanates with alcohols should be carried out in inert solvents. Such reactions in the absence of solvents often occur with explosive violence, Wischmeyer(1969). (REACTIVITY, 1999)STABILITY: When exposed to heat above 392 F, this compound undergoes an exothermic and self-sustaining decomposition reaction. In a closed container, the pressure buildup can be rapid enough to cause an explosion.REACTIVITY: This compound is a weak base. (NTP, 1992)AIR AND WATER REACTIONS: It is soluble in water with release of heat. (REACTIVITY, 1999)None reported; after prolonged contact with water, solution reverts to soluble calcium salts and amorphous silica.STABILITY: This compound becomes brown on exposure to air. (NTP, 1992)AIR AND WATER REACTIONS: a lachrymator (REACTIVITY, 1999)CHEMICAL PROFILE: Colorless, oily liquid, moderately toxic, flammable. A storage hazard above 32 deg. C, involved in several industrial explosions caused by violent, exothermic polymerization [Bond, J., Loss Prev. Bull., 1985, (065), p. 25]. Polymerization becomes self-sustaining above 95 deg. C [MCA SD-37, 1971]. Violent polymerization leading to explosion may be initiated by peroxides (e.g., di-tert-butyl peroxide, dibenzoyl peroxide), butyllithium, initiators (e.g., azoisobutyronitrile). Reacts violently on contact with strong acids (sulfuric acid, oleum, chlorosulfonic acid), strong oxidizeres [Lewis, 3rd ed., 1993, p. 1185]. Reacts with oxygen above 40 deg. C to form explosive peroxide [Barnes, C. E. et al., J. Amer. Chem. Soc., 1950, 72, p. 210]. Oxidizes readily in air to form unstable peroxides that may explode spontaneously (Bretherick 1979 p.151-154, 164). Mixing styrene in equal molar portions with any of the following substances in a closed container caused the temperature and pressure to increase: chlorosulfonic acid, oleum, and sulfuric acid (NFPA 1991). (REACTIVITY, 1999)LVAL 9y@ Explosive Limit"Exposure Symptoms"87-88 TLV-TWA ppm&87-88Keep sparks, flames, and other sources of ignition away. Keep sparks, flames, and other sources of ignition away. Keep material out of water sources and sewers. ( AAR, 1999)Attempt to stop leak if without undue personnel hazard. ( AAR, 1999)Keep sparks, flames, and other sources of ignition away. Keep material out of water sources and sewers. ( AAR, 1999)Keep sparks, flames, and other sources of ignition away. Keep material out of water sources and sewers. ( AAR, 1999)Neutralizing Agents for Acids and Caustics: Flush with water (USCG, 1999)Keep sparks, flames, and other sources of ignition away. Keep material out of water sources and sewers. ( AAR, 1999)Avoid inhalation and skin contact. (EPA, 1998)Neutralizing Agents for Acids and Caustics: Dilute with water (USCG, 1999)Keep sparks, flames, and other sources of ignition away. Keep material out of water sources and sewers. Build dikes to contain flow as necessary. ( AAR, 1999)Keep sparks, flames, and other sources of ignition away. Keep material out of water sources and sewers. Build dikes to contain flow as necessary. Attempt to stop leak if without undue personnel hazard. Use water spray to knock-down vapors. Combustion products include corrosive or toxic vapors. Land spill: Dig a pit, pond, lagoon, holding area to contain liquid or solid material. Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete. Absorb bulk liquid with fly ash or cement powder. Water spill: Use natural barriers or oil spill control booms to limit spill travel. Remove trapped material with suction hoses. ( AAR, 1999)Keep sparks, flames, and other sources of ignition away. Keep material out of water sources and sewers. Build dikes to contain flow as necessary. Attempt to stop leak if without undue personnel hazard. ( AAR, 1999)Keep sparks, flames, and other sources of ignition away. Keep material out of water sources and sewers. Build dikes to contain flow as necessary. Use water spray to knock-down vapors. Vapor knockdown water is corrosive or toxic and should be diked for containment. Land spill: Dig a pit, pond, lagoon, holding area to contain liquid or solid material. Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete. Apply "universal" gelling agent to immobilize spill. Water spill: Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom. Remove trapped material with suction hoses. If dissolved, in region of 10 ppm or greater concentration, apply activated carbon at ten times the spilled amount. Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates. ( AAR, 1999)Keep sparks, flames, and other sources of ignition away. Keep material out of water sources and sewers. Build dikes to contain flow as necessary. Attempt to stop leak if without undue personnel hazard. Use water spray to knock-down vapors. Land spill: Dig a pit, pond, lagoon, holding area to contain liquid or solid material. Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete. Absorb bulk liquid with fly ash, cement powder, or commercial sorbents. Apply "universal" gelling agent to immobilize spill. Apply approriate foam to diminish vapor and fire hazard. Water spill: Use natural barriers or oil spill control booms to limit spill travel. Use surface active agent (e.g. detergent, soaps, alcohols), if approved by epa. Inject "universal" gelling agent to solidify encircled spill and increase effectiveness of booms. If dissolved, in region of 10 ppm or greater concentration, apply activated carbon at ten times the spilled amount. Remove trapped material with suction hoses. Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates. ( AAR, 1999)LVAL(siSigns and Symptoms of Acute Benzyl Chloride Exposure: Benzyl chloride may be very irritating to the skin, eyes, and mucous membranes. Eye irritation may be severe, and permanent eye damage may result. Lacrimation (tearing) is common. Other signs and symptoms of acute exposure may include headache, dizziness, weakness, fatigue, irritability, itching of the skin, profuse sweating, insomnia, tremors, unsteadiness, and central nervous system depression. Gastrointestinal effects may include nausea, vomiting, cramps, anorexia, and diarrhea. Pulmonary edema and disturbance of liver function may also occur. Emergency Life-Support Procedures: Acute exposure to benzyl chloride may require decontamination and life support for the victims. Emergency personnel should wear protective clothing appropriate to the type and degree of contamination. Air-purifying or supplied-air respiratory equipment should also be worn, as necessary. Rescue vehicles should carry supplies such as plastic sheeting and disposable plastic bags to assist in preventing spread of contamination. Inhalation Exposure: 1. Move victims to fresh air. Emergency personnel should avoid self-exposure to benzyl chloride. 2. Evaluate vital signs including pulse and respiratory rate, and note any trauma. If no pulse is detected, provide CPR. If not breathing, provide artificial respiration. If breathing is labored, administer oxygen or other respiratory support. 3. Obtain authorization and/or further instructions from the Localized hospital for administration of an antidote or performance of other invasive procedures. 4. Transport to a health care facility. Dermal/Eye Exposure: 1. Remove victims from exposure. Emergency personnel should avoid self- exposure to benzyl chloride. 2. Evaluate vital signs including pulse and respiratory rate, and note any trauma. If no pulse is detected, provide CPR. If not breathing, provide artificial respiration. If breathing is labored, administer oxygen or other respiratory support. 3. Remove contamLVAL Explosive Limit*Lower Explosive Limit"Exposure Symptoms"87-88 TLV-TWA ppm&87-88 TLV-TWA mg/m3$87-88 TLV-STEL ppm(87-88 TLV-STEL mg/m387-88 TLV-C ppm"87-88 TLV-C mg/m387-88 TLV Notes 87-88 ACGIH Skin86 REL-TWA ppm 86 REL-TWA mg/m386 REL-STEL ppm"86 REL-STEL mg/m386 REL-C ppm86 REL-C mg/m386 REL Notes86 NIOSH SKIN886/87 Carcinogen DesignationTLV-TWA f/ccTLV-STEL f/ccTLV-C f/ccPEL-TWA f/ccPEL-STEL f/ccPEL-C f/ccREL-TWA f/ccREL-STEL f/ccREL-C f/cc$87-88 TLV-TWA f/ccinated clothing as soon as possible. 4. If eye exposure has occurred, eyes must be flushed with lukewarm water for at least 15 minutes. 5. Wash exposed skin areas THOROUGHLY with soap and water. 6. Obtain authorization and/or further instructions from the Localized hospital for administration of an antidote or performance of other invasive procedures. 7. Transport to a health care facility. Ingestion Exposure: 1. Evaluate vital signs including pulse and respiratory rate, and note any trauma. If no pulse is detected, provide CPR. If not breathing, provide artificial respiration. If breathing is labored, administer oxygen or other respiratory support. 2. Obtain authorization and/or further instructions from the Localized hospital for administration of an antidote or performance of other invasive procedures. 3. Give the victims water or milk: children up to 1 year old, 125 mL (4 oz or 1/2 cup); children 1 to 12 years old, 200 mL (6 oz or 3/4 cup); adults, 250 mL (8 oz or 1 cup). Water or milk should be given only if victims are conscious and alert. 4. Activated charcoal may be administered if victims are conscious and alert. Use 15 to 30 g (1/2 to 1 oz) for children, 50 to 100 g (1-3/4 to 3-1/2 oz) for adults, with 125 to 250 mL (1/2 to 1 cup) of water. 5. Promote excretion by administering a saline cathartic or sorbitol to conscious and alert victims. Children require 15 to 30 g (1/2 to 1 oz) of cathartic; 50 to 100 g (1-3/4 to 3-1/2 oz) is recommended for adults. 6. Transport to a health care facility. (EPA, 1998)LVALf3!g#p._K"Exposure Symptoms"87-88 TLV-TWA ppm&87-88 TLV-TWA mg/m3$87-88 TLV-STEL pEyes: Irrigate immediately; Skins: Soap wash prompt; InhalatioEyes: Irrigate immediately; Skins: Soap wash prompt; Inhalation: Respiratory support; Ingestion: Medical attention immediatelyEyes: Irrigate immediately; Skins: Soap wash; Inhalation: Respiratory supportEyes: Irrigate immediately; Skins: Soap wash; Inhalation: Fresh airEyes: Irrigate immediately; Skins: Soap wash; Inhalation: Fresh airEyes: Irrigate immediately; Skins: Soap wash; Inhalation: Fresh airEyes: Irrigate immediately; Skins: Soap wash; Inhalation: Fresh airEyes: Irrigate immediately; Skins: Water flush prompt; Inhalation: Fresh air; Ingestion: Medical attention immediatelyEyes: Irrigate immediately; Skins: Soap wash; Inhalation: Respiratory support; Ingestion: Medical attention immediatelyINHALATION: remove to fresh air. EYES: wash with water for 20 min. call a physician. SKIN: wash with water. (USCG, 1999)SKIN OR EYE CONTACT: irrigate affected area with water for 15 min. (USCG, 1999)Eyes: Irrigate immediately; Skins: Soap wash prompt; Inhalation: Respiratory support; Ingestion: Medical attention immediatelyEyes: Irrigate immediately; Skins: Soap wash; Inhalation: Fresh air; Ingestion: Medical attention immediatelyEYES or SKIN: flush with water; treat caustic burns. (USCG, 1999)Eyes: Frostbite; Skins: Frostbite; Inhalation: Respiratory supportRemove victim to fresh air, give artificial respiration and oxygen if breathing has stopped, and call a physician. (USCG, 1999)Remove from exposure; support respiration. (USCG, 1999)Eyes: Irrigate immediately; Skins: Soap wash; Inhalation: Respiratory support; Ingestion: Medical attention immediatelyEyes: Irrigate immediately; Inhalation: Fresh airEyes: Irrigate immediately; Inhalation: Fresh airEyes: Irrigate immediately; Inhalation: Fresh airEyes: Irrigate immediately; Inhalation: Fresh airEye: Irrigate immediately; Skin: Soap wash; Inhalation: Fresh airEYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment. INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of Breathing, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing. INGESTION: DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a p